Petro-SIM 7.5 improvements to Unit Operations

New Features in the Water Electrolyser unit operation

We are introducing this new unit operation, the water electrolyser produces hydrogen (and oxygen) from water and three types of electrolysers are available:

• Hydrogen crossover models

An important aspect in the operation of electrolysers is the hydrogen crossover to the anode side, also known as HTO. Hydrogen can be present in the oxygen produced by the electrolyser, posing a great hazard if its concentration exceeds 2% has been agreed in the International Standard ISO22734 (Hydrogen Generators using Water Electrolysis - Industrial, Commercial and Residential Applications). The hydrogen crossover is calculated from the mass flux of hydrogen from the cathode to the anode side across the membrane separating these electrodes. The model implemented in Petro-SIM v7.5 considers the contributions of diffusion and convection to the mass flux.

Hydrogen Crossover page

• Independent recycle streams for both the cathode and anode side

Majority of electrolyser designs segregate the recycle streams from the cathode and anode side. This can now be specified in Petro-SIM v7.5 and depending on the type of electrolyser, the material balance will depend on the side on which water is converted into hydrogen and oxygen.

Independent Recycle and Feed Streams

• Two feed streams

Recycle streams from each side of the electrolyser are segregated and sent independently back to the corresponding electrode side in the electrolyser.

• Automatic saturation of water, hydrogen and oxygen

Assuming that the oxygen and hydrogen separators are integrated inside the unit operation, the User can specify water saturation of the hydrogen and oxygen outlet streams. Similarly, the User can specify oxygen and/or hydrogen saturation in the recycle streams.

Water, Hydrogen and Oxygen Saturation Options

• Override Faraday efficiency

Give the User the ability to override the calculated Faraday efficiency.

• Plot polarization curve

Petro-SIM plots the polarization curves in the Electrolyser unit operation. The operating point is also plotted on the polarization curve.

Polariation Curves Plot

Base Delta

• New in=out mode:
  + This new functionality in the Base Delta unit op just lets the material through without applying any base delta vectors
  + One example of application could be a situation when during the initial steps of the plant start up, there is material recirculating through the reactors, and no reactions are taking place
  

New In=Out option

• Give user built base delta tables an easy way to initialize to zero:
  + When building a base delta table manually in a Base Delta unit op, the User can choose to fill all <empty> values with 0.0
  

New Fill Empty cells option

• New ability to specify stream type per cut in base delta op synthesis cuts:
  + The Base Delta unit operation allows the ability to specify the stream type for synthesis
  + Even if having a fully configured Base Delta page on the reactors working (generating multiple products, etc.), this new functionality is necessary for extended usage of the Base-Delta operation
  

New specify stream type option